If the pcv valve is referring to some sort of crankcase pressure valve, if it's broken then you will get either suction or air blowing out of the oil filler cap with the engine running and the cap removed (rather harshly, a little bit is normal).
You have checked the more obvious like the brake booster pipe and engine breathers?. If you can't find it by using the water method (you must have a pretty big leak for the idle to be that rough!) you'll have to strip the hose & pipe bits down, then examine them all one by one unfortunately